Scanning tunneling microscope
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Image of reconstruction on a clean Gold(100) surface.
STM image of self-assembled supramolecular chains of the organic semiconductor Quinacridone on Graphite.
Scanning tunneling microscope (STM) is a powerful technique for viewing surfaces at the atomic level. Its development in 1981 earned its inventors, Gerd Binnig and Heinrich Rohrer (at IBM Zürich), the Nobel Prize in Physics in 1986[1][2]. STM probes the density of states of a material using tunneling current. For STM, good resolution is considered to be 0.1 nm lateral resolution and 0.01 nm depth resolution[3]. The STM can be used not only in ultra high vacuum but also in air and various other liquid or gas ambients, and at temperatures ranging from near 0 kelvin to a few hundred degrees Celsius[4].
The STM is based on the concept of quantum tunneling. When a conducting tip is brought very near to a metallic or semiconducting surface, a bias between the two can allow electrons to tunnel through the vacuum between them. For low voltages, this tunneling current is a function of the local density of states (LDOS) at the Fermi level, Ef, of the sample[4]. Variations in current as the probe passes over the surface are translated into an image. STM can be a challenging technique, as it requires extremely clean surfaces and sharp tips.
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